Uh oh, sry for the lousy previous one, I'll try to explain things in more detail:
1280x800 Standard Filter, TV Aspect, Max scaling - presumably ok Aspect Ratio;
1280x800 NTSC Filter, TV Aspect, Max scaling - probably 1:1 (looks like);
640x480 NTSC Filter, TV Aspect, Max scaling - wider than 640x480 Standard Filter, TV Aspect, Max but not totally streched to 4:3;
Also in 1280x800, when unchecking TV Aspect in NTSC and menus and having Standard Filter On before, results in having 2x and 3x scaling ratios additionally with NTSC, which aren't working when you again check TV Aspect in menus (because normally in that mode there is only 1x and Max), but it's really a minor. Ideally, when you would check back TV Aspect in menus it should hide 2x and 3x or just work with these.